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15.2 MB
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7BC9F1FD40BC106D35FAFAB89724B47D9A4784F1
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Aug. 29, 2025, 3:03 p.m.
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(Last updated: Aug. 29, 2025, 3:06 p.m.)
| File | Size |
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| Kapadiya K., Jivani A. Stereochemistry 2023.pdf | 15.2 MB |
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SOURCE: Kapadiya K., Jivani A. Stereochemistry 2023
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COVER
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MEDIAINFO
Textbook in PDF format The collection of chapters in this first volume of Stereochemistry – Basic to Advances inOrganic Chemistry covers a range of topics that reflects both the evolution of the field of stereochemistry and the most exciting advances that presage its future. Thus, it wasexpressly by design that there be conceptually focused chapters on the basic principles of molecular chirality and asymmetric amplification to perfectly predict the structure of organicmolecules. The goal, as in the first edition, is to give equal weight to the fundamental aspects of thestudy of stereochemistry. The history of organic chemistry goes back to the days of FriedrichWohler, two centuries ago. The stereochemical underpinnings of organic chemistry were set by Louis Pasteur, and the concept of chirality was advanced by Lord Kelvin, nearly a centurylater. The first stereochemical notation – that of the asymmetric carbon atom– had to await the Cahn-Ingold-Prelog (CIP) R/S rules – a half-century later; it took yet another quartercentury for the E/Z configurational notation for double bonds to be formulated. Indeed, thedevelopment of organic stereochemical language has lagged and continues tolagexperimental organic chemistry. In the last quarter-century or so, there have been onlytwoseminal contributions – both by Kurt Mislow and his coworkers – ones that have clarifiedthebasic concepts of stereotopicity and chirotopicity. Since last two decades, scientists areworking very hard to establish the unknown organic structure through the correlation of stereochemical aspects and predicting its potency and efficiency based on these parameters. Also, the national universities and central examinations organizations focused more toincorporate the stereochemistry in basics to the complex molecular framework. The past years have witnessed a rapid development of biochemistry and molecular biology. The chemical structures of many complex biopolymers such as proteins andnucleicacids have been elucidated. Moreover, the understanding of the stereochemical details of many important transformations catalyzed by various metal and non-metal reactions reflect the structural complexity of organic, inorganic and biomolecular chemistry. This book provides an insightful analysis of the foundations of molecular chirality, topological chirality, definitions of chirality measures, rules applying during nomenclature, set of rules for predicting the stereochemistry, dynamic stereochemical concepts, and most important, practice with suitable examples for the readers. Nevertheless, students will oftenwish to pursue individual topics further. This part of the work is an attempt to present theelements of a simple, uniform and comprehensive language of organic stereochemistry. Aneffort has therefore been made to guide the reader to give a piece of small informationthat isquite useful to understand the concepts. Furthermore, in a graduate course, students shouldbe encouraged to consult primary sources. Authors are hoping that this book will not onlybe of interest to specialists but will also provide general information useful to organic chemists, biochemists and molecular biologists for their research and reference work duringinternational publications
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